$A$
Since the primary key contains only one attribute, there is no partial dependency.
So, relation $R$ is in $2NF$.
Now check for $3NF$.
Given dependency:
$D\rightarrow E$
Here, $D$ is not a super key and $E$ is a non-prime attribute.
So, relation is not in $3NF$.
Therefore, the highest normal form of relation $R$ is:
$2NF$
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and More.